Platinum compounds & chloroplatinates

Chloroplatinic acid hexahydrate is the standard platinum precursor for platinum catalysts (Adams' catalyst PtO2, Pt/C, Speier's and Karstedt's hydrosilylation catalysts), electroplating and platinising of electrodes, platinum nanoparticles and fuel-cell electrocatalysts. Like all soluble chloroplatinates it is a potent respiratory and skin sensitiser and must be handled in a fume hood with full containment of dust and aerosols. Each lot is supplied with a platinum assay and full certificate of analysis.

Grade

≥99.9% (metals basis); Pt ≈ 38%

Pack sizes

1 g, 5 g, 25 g

Potassium hexachloroplatinate(IV) is a yellow to orange crystalline platinum(IV) salt, sparingly soluble in water, used as a stable platinum precursor for supported Pt catalysts and fuel-cell electrocatalysts (Pt/C by reduction), platinum nanoparticles and sols, and as a defined platinum standard. It is the classical gravimetric form for potassium and a key intermediate in platinum refining. A respiratory and skin sensitiser: handle only with dust containment. Approximately 40% platinum by mass; each lot is assayed and ships with a certificate of analysis.

Grade

≥99.9% (metals basis); Pt ≈ 40%

Pack sizes

1 g, 5 g, 25 g

Potassium tetrachloroplatinate(II) is a ruby-red, water-soluble platinum(II) salt and the standard starting material for platinum(II) coordination chemistry: cisplatin and other platinum anticancer complexes, Zeise's salt, platinum phosphine and diimine complexes, platinum porphyrins and phosphorescent emitters. It is also used for platinum nanoparticles and shape-controlled nanocrystals, Pt/C catalysts and platinum plating baths. A respiratory and skin sensitiser: handle only with dust containment. Approximately 47% platinum by mass; supplied with a lot-specific assay.

Grade

≥99.9% (metals basis); Pt ≈ 47%

Pack sizes

1 g, 5 g, 25 g

Ammonium hexachloroplatinate(IV) is a yellow to orange crystalline platinum(IV) salt, sparingly soluble in water, that decomposes cleanly on heating to platinum sponge, the classical route to high-purity platinum and platinum black. It is used to prepare supported platinum catalysts, fuel-cell electrocatalysts, platinum nanoparticles and platinum coatings, and as the platinum intermediate in refining and recovery. A respiratory and skin sensitiser: handle only with dust containment. Approximately 44% platinum by mass; each lot is assayed and released with a certificate of analysis.

Grade

≥99.9% (metals basis); Pt ≈ 44%

Pack sizes

1 g, 5 g, 25 g